The effect of substituents on triply bonded boronantimony molecules: a theoretical approach-Reference-Cited by-同舟云学术

The effect of substituents on triply bonded boronantimony molecules: a theoretical approach

Published:2017 Issue:11 Volume:19 Page:8026-8033
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lu Jia-Syun¹²³⁴,Yang Ming-Chung¹²³⁴,Su Ming-Der¹²³⁴⁵^ORCID

Affiliation:

1. Department of Applied Chemistry

2. National Chiayi University

3. Chiayi 60004

4. Taiwan

5. Department of Medicinal and Applied Chemistry

Abstract

Theoretical calculations using the M06-2X, B3PW91 and B3LYP levels of theory demonstrate that the attached substituents (R) play a decisive role in determining the stability of triply bonded RBSbR molecules. Theoretical evidence shows that, from the kinetic viewpoint, only bulkier substituents have a significant stabilizing effect on the formation of the triply bonded RBSbR compounds.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP00421D

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