Not the sum of their parts: understanding multi-donor interactions in symmetric and asymmetric TADF emitters

Author:

Danos Andrew1ORCID,Gudeika Dalius2ORCID,Kukhta Nadzeya A.34ORCID,Lygaitis Ramunas2,Colella Marco1,Higginbotham Heather F.1,Bismillah Aisha N.3,McGonigal Paul R.3ORCID,Grazulevicius Juozas Vidas2ORCID,Monkman Andrew P.1ORCID

Affiliation:

1. Department of Physics, Durham University, South Road, Durham, DH1 3LE, UK

2. Department of Polymer Chemistry and Technology, Kaunas University of Technology, Kaunas 51423, Lithuania

3. Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, UK

4. Materials Science and Engineering Department, University of Washington, Seattle, Washington 98195, USA

Abstract

Electronic communication uncovered between donor groups in a pair of D–A–D TADF emitters lowers their triplet energies, and shows that they cannot be described purely as combinations of the equivalent D–A systems.

Funder

Horizon 2020 Framework Programme

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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