Mechanistic investigation of a visible light mediated dehalogenation/cyclisation reaction using iron(iii), iridium(iii) and ruthenium(ii) photosensitizers-Reference-Cited by-同舟云学术

Mechanistic investigation of a visible light mediated dehalogenation/cyclisation reaction using iron(iii), iridium(iii) and ruthenium(ii) photosensitizers

Published:2021 Issue:24 Volume:11 Page:8037-8051
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Aydogan Akin¹,Bangle Rachel E.²^ORCID,De Kreijger Simon¹,Dickenson John C.²^ORCID,Singleton Michael L.¹^ORCID,Cauët Emilie³^ORCID,Cadranel Alejandro⁴⁵⁶^ORCID,Meyer Gerald J.²^ORCID,Elias Benjamin¹^ORCID,Sampaio Renato N.²⁷^ORCID,Troian-Gautier Ludovic¹^ORCID

Affiliation:

1. Université catholique de Louvain (UCLouvain), Institut de la Matière Condensée et des Nanosciences (IMCN), Molecular Chemistry, Materials and Catalysis (MOST), Place Louis Pasteur 1, bte L4.01.02, 1348 Louvain-la-Neuve, Belgium

2. Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina, 27599-3290, USA

3. Spectroscopy, Quantum Chemistry and Atmospheric Remote Sensing (CP 160/09), Université libre de Bruxelles, 50 av. F. D. Roosevelt, B-1050 Brussels, Belgium

4. Department of Chemistry and Pharmacy, Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstr. 3, 91058 Erlangen, Germany

5. Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Química Inorgánica, Analítica y Química Física, Pabellón 2, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina

6. CONICET – Universidad de Buenos Aires. Instituto de Química Física de Materiales, Medio Ambiente y Energía (INQUIMAE), Pabellón 2, Ciudad Universitaria, C1428EHA, Buenos Aires, Argentina

7. Chemistry Division, Brookhaven National Laboratory, Upton, NY 11973-5000, USA

Abstract

The identification of reaction mechanisms unique to the iron, ruthenium, and iridium PS represents progress towards the long-sought goal of utilizing earth-abundant, first-row transition metals for emerging energy and environmental applications.

Funder

Fonds De La Recherche Scientifique - FNRS

Basic Energy Sciences

Division of Graduate Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY01771C

Reference74 articles.

1. Electronic structure in the transition metal block and its implications for light harvesting