Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles-Reference-Cited by-同舟云学术

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Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles

Published:2015 Issue:10 Volume:6 Page:5922-5927
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Zuolun¹²³⁴⁵,Edkins Robert M.⁶⁷⁸⁹,Haehnel Martin⁶⁷⁸⁹,Wehner Marius⁶⁷⁸⁹,Eichhorn Antonius⁶⁷⁸⁹,Mailänder Lisa⁶⁷⁸⁹,Meier Michael⁶⁷⁸⁹,Brand Johannes⁶⁷⁸⁹,Brede Franziska⁶⁷⁸⁹,Müller-Buschbaum Klaus⁶⁷⁸⁹,Braunschweig Holger⁶⁷⁸⁹,Marder Todd B.⁶⁷⁸⁹

Affiliation:

1. State Key Laboratory of Supramolecular Structure and Materials

2. College of Chemistry

3. Jilin University

4. Changchun 130012

5. P. R. China

6. Institut für Anorganische Chemie

7. Julius-Maximilians-Universität Würzburg

8. 97074 Würzburg

9. Germany

Abstract

Boroles with a fluoromesityl group on the B atom have greatly improved air stability compared to their mesityl analogues.

Funder

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02205C

Reference62 articles.

1. Dibenzometallacyclopentadienes, boroles and selected transition metal and main group heterocyclopentadienes: Synthesis, catalytic and optical properties

2. Recent developments in the chemistry of antiaromatic boroles

3. Free Boroles

4. Structural Evidence for Antiaromaticity in Free Boroles

5. Direct functionalization at the boron center of antiaromatic chloroborole

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