Molecular crystalline capsules that release their contents by light

Author:

Nagai Akira1,Nishimura Ryo1ORCID,Hattori Yohei1ORCID,Hatano Eri1,Fujimoto Ayako1,Morimoto Masakazu2ORCID,Yasuda Nobuhiro3,Kamada Kenji4ORCID,Sotome Hikaru5ORCID,Miyasaka Hiroshi5ORCID,Yokojima Satoshi6ORCID,Nakamura Shinichiro7ORCID,Uchida Kingo1ORCID

Affiliation:

1. Department of Materials Chemistry, Faculty of Science and Technology, Ryukoku University, Seta, Otsu, Shiga 520-2194, Japan

2. Department of Chemistry and Research Center for Smart Molecules, Rikkyo University, 3-34-1 Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan

3. Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198, Japan

4. Nanomaterials Research Institute (NMRI), National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan

5. Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan

6. School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan

7. Nakamura Laboratory, RIKEN Cluster for Science, Technology and Innovation Hub, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan

Abstract

A novel diarylethene formed “crystalline capsules” containing liquid inclusions, and chemicals trapped in the capsules were released by photoinduced breaking. Operations by multiphoton and linear polarized light were demonstrated.

Funder

Japan Society for the Promotion of Science

Ministry of Education, Culture, Sports, Science and Technology

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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