Harnessing the potential diversity of resinic diterpenes through visible light-induced sensitized oxygenation coupled to Kornblum–DeLaMare and Hock reactions
Author:
Affiliation:
1. Muséum National d'Histoire Naturelle
2. CNRS
3. Unité Molécules de Communication et Adaptation des Micro-organismes (UMR 7245)
4. Sorbonne Universités
5. 75005 Paris
Abstract
A biomimetic procedure for the late functionalization of resinic acids is reported, implementing photooxygenation by singlet oxygen, using visible light and a photosensitized, combined to the Kornblum–DeLaMare reaction or the Hock rearrangement.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/QO/C7QO00633K
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