Performance and failure mechanisms of alkaline zinc anodes with addition of calcium zincate (Ca[Zn(OH)3]2·2H2O) under industrially relevant conditions

Author:

Yang Patrick K.123ORCID,Turney Damon E.3ORCID,Nyce Michael3,Wygant Bryan R.4ORCID,Lambert Timothy N.45ORCID,O'Brien Stephen123ORCID,Yadav Gautam G.6ORCID,Weiner Meir6,Yang Shinju6,Hawkins Brendan E.6ORCID,Banerjee Sanjoy376

Affiliation:

1. Ph.D. Program in Chemistry, The Graduate Center of the City University of New York, 365 Fifth Avenue, New York, New York 10016, USA

2. Department of Chemistry and Biochemistry, The City College of New York, Marshak Science Building, Room 1024, 160 Convent Avenue, New York, NY 10031, USA

3. The CUNY Energy Institute, The City College of New York, City University of New York, Steinman Hall, 160 Convent Avenue, New York, NY 10031, USA

4. Department of Photovoltaics and Materials Technology, Sandia National Laboratories, Albuquerque, NM 87185, USA

5. Center for Integrated Nanotechnologies, Sandia National Laboratories, Albuquerque, NM 87185, USA

6. Urban Electric Power Inc., Pearl River, NY 10965, USA

7. Department of Chemical Engineering, The City College of New York, Steinman Hall, 160 Convent Avenue, New York, NY 10031, USA

Abstract

Various zinc anodes with increasing calcium zincate (0%, 30%, 70%, 100%) were cycled at 50% theoretical Zn utilization to investigate cycle life and estimated cost. Failure mechanisms of majority 70% Zn/30% CaZn anodes are compared with pure CaZn.

Funder

National Science Foundation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

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