First-principles microkinetic analysis of Lewis acid sites in Zn-ZSM-5 for alkane dehydrogenation and its implication to methanol-to-aromatics conversion-Reference-Cited by-同舟云学术

First-principles microkinetic analysis of Lewis acid sites in Zn-ZSM-5 for alkane dehydrogenation and its implication to methanol-to-aromatics conversion

Published:2021 Issue:6 Volume:11 Page:2031-2046
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Du Yu-Jue¹²³⁴,Hu Wen-De¹²³⁴,Wang Chuan-Ming¹²³⁴^ORCID,Zhou Jian¹²³⁴^ORCID,Yang Guang¹²³⁴,Wang Yang-Dong¹²³⁴,Yang Wei-Min¹²³⁴

Affiliation:

1. State Key Laboratory of Green Chemical Engineering and Industrial Catalysis

2. Sinopec Shanghai Research Institute of Petrochemical Technology

3. Shanghai 201208

4. China

Abstract

Stabilities and dehydrogenation activities of butane and cyclohexane on four different Zn sites in ZSM-5 zeolite were theoretically revealed. ZnOH⁺ was identified as the most active site at low temperature and the activity increases with the sequence of dehydrogenation.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D0CY02318C

Reference83 articles.

1. Beyond Oil and Gas: The Methanol Economy

2. Methanol-to-hydrocarbons: catalytic materials and their behavior