Germanium- and tin-bridged diazulenylmethyl cations: effects of group 14 elements on the structure and properties of π-extended cations-Reference-Cited by-同舟云学术

Germanium- and tin-bridged diazulenylmethyl cations: effects of group 14 elements on the structure and properties of π-extended cations

Published:2023 Issue:25 Volume:52 Page:8631-8635
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Murai Masahito¹^ORCID,Ito Mako¹,Takahashi Satoshi¹,Yamaguchi Shigehiro¹²^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science and Integrated Research Consortium on Chemical Science (IRCCS), Nagoya University, Furo, Chikusa, Nagoya 464-8602, Japan

2. Institute of Transformative Bio-Molecules (WPI-ITbM), Nagoya University, Furo, Chikusa, Nagoya 464-8601, Japan

Abstract

Germanium- and tin-bridged diazulenylmethyl cations were synthesized, where the heavier elements increased their chemical stability, and affected the J-type aggregated absorption and fluorescence properties relative to those of the silicon-congeners.

Funder

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01491F

Reference42 articles.

1. The photochemistry and photophysics of triphenylmethane dyes in solid and liquid media

2. Cationic triangulenes and helicenes: synthesis, chemical stability, optical properties and extended applications of these unusual dyes

3. Structure and Nanostructure in Ionic Liquids