Enantiomeric resolution and X-ray optical activity of a tricobalt extended metal atom chain

Author:

Srinivasan Anandi12345,Cortijo Miguel12345ORCID,Bulicanu Vladimir12345,Naim Ahmad16345ORCID,Clérac Rodolphe12345ORCID,Sainctavit Philippe789110,Rogalev Andrei11124,Wilhelm Fabrice11124,Rosa Patrick16345ORCID,Hillard Elizabeth A.12345ORCID

Affiliation:

1. CNRS

2. CRPP

3. F-33600 Pessac

4. France

5. Univ. Bordeaux

6. ICMCB

7. Institut de Mineralogie

8. de Physique des Materiaux et de Cosmochimie

9. UMR 7590

10. UPMC

11. European Synchrotron Radiation Facility (ESRF)

12. F-38043 Grenoble

Abstract

Enantiopure single crystals of extended metal atom chains display exceptionally large optical X-ray dichroisms at the Co K-edge.

Funder

Agence Nationale de la Recherche

H2020 Marie Skłodowska-Curie Actions

Université de Bordeaux

European Synchrotron Radiation Facility

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference39 articles.

1. From Homonuclear Metal String Complexes to Heteronuclear Metal String Complexes

2. M. Majumdar and J. K.Bera , Supramolecular and Self-Assembled Metal-Containing Materials , in Macromolecules Containing Metal and Metal-Like Elements , ed. A. Abd-El Aziz , C. E. Carraher , C. U. Pittman and M.Zeldin , John Wiley & Sons, Inc. , 2009 , vol. 9 , pp. 182–253

3. J. F. Berry , in Multiple Bonds between Metal Atoms , ed. F. A. Cotton , C. A. Murillo and R. A. Walton , Springer U.S. , 2005 , pp. 669–706

4. New Linear Tricobalt Complex of Di(2-pyridyl)amide (dpa), [Co3(dpa)4(CH3CN)2][PF6]2

5. Resolution of Enantiomers in Solution and Determination of the Chirality of Extended Metal Atom Chains

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