Porphyrinoids as a platform of stable radicals

Author:

Shimizu Daiki12345ORCID,Osuka Atsuhiro12345ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Kyoto University

4. Kyoto 606-8502

5. Japan

Abstract

This review surveys four types of stable porphyrinoid radical and covers their synthetic methods and properties. The remarkable radical-stabilizing abilities of porphyrinoid stem from their unique macrocyclic conjugated systems with high electronic and structural flexibilities.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference123 articles.

1. Handbook of Porphyrin Science , ed. K. M. Kadish , K. M. Smith and R. Guilard , World Scientific Publishing , Singapore , 2010 , vol. 1–25

2. The Porphyrin Handbook , ed. K. M. Kadish , K. M. Smith and R. Guilard , Academic Press , San Diego , 2000 , vol. 1–10

3. Subporphyrins: A Legitimate Ring-Contracted Porphyrin with Versatile Electronic and Optical Properties

4. Subphthalocyanines, Subporphyrazines, and Subporphyrins: Singular Nonplanar Aromatic Systems

5. Recent Advances in Subporphyrins and Triphyrin Analogues: Contracted Porphyrins Comprising Three Pyrrole Rings

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