Synthesis and catalytic activity of N-heterocyclic silylene (NHSi) cobalt hydride for Kumada coupling reactions

Author:

Qi Xinghao12345,Sun Hongjian12345ORCID,Li Xiaoyan12345ORCID,Fuhr Olaf6789,Fenske Dieter6789

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Key Laboratory of Special Functional Aggregated Materials

3. Ministry of Education

4. Shandong University

5. 250199 Jinan

6. Institut für Nanotechnologie (INT) und Karlsruher Nano-Micro-Facility (KNMF)

7. Karlsruher Institut für Technologie (KIT)

8. 76344 Eggenstein-Leopoldshafen

9. Germany

Abstract

The first silylene Co(iii) hydride6, an efficient catalyst for Kumada cross-coupling reactions, was preparedviaSi–H activation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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