Cooperative catalytic methoxycarbonylation of alkenes: uncovering the role of palladium complexes with hemilabile ligands

Author:

Dong Kaiwu123ORCID,Sang Rui123,Wei Zhihong123ORCID,Liu Jie123ORCID,Dühren Ricarda123,Spannenberg Anke123,Jiao Haijun123ORCID,Neumann Helfried123,Jackstell Ralf123,Franke Robert45367,Beller Matthias123ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock

2. Rostock

3. Germany

4. Evonik Performance Materials GmbH

5. 45772 Marl

6. Lehrstuhl für Theoretische Chemie

7. Ruhr-Universität Bochum

Abstract

Mechanistic studies of the catalyst [Pd2(dba)3/1,1′-bis(tert-butyl(pyridin-2-yl)phosphanyl)ferrocene,L2] for olefin alkoxycarbonylation reactions are described.

Funder

Leibniz-Gemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference40 articles.

1. J. F. Hartwig , Organotransition Metal Chemistry: From Bonding to Catalysis , University Science Books , Sausalito , 2009

2. R. Peters , Cooperative Catalysis: Designing Efficient Catalysts for Synthesis , Wiley-VCH Verlag GmbH & Co. KGaA , 2015

3. P. Kalck , Homo- and Heterobimetallic Complexes in Catalysis: Cooperative Catalysis , Springer International Publishing , 2016

4. The NH Functional Group in Organometallic Catalysis

5. Hydrogenation and Dehydrogenation Iron Pincer Catalysts Capable of Metal–Ligand Cooperation by Aromatization/Dearomatization

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