Controlled packing of chiral assembly scaffolds to promote chiral J-aggregation of carbocyanine dyes

Author:

Ryu Naoya1ORCID,Yamamoto Yusei2,Okazaki Yutaka3ORCID,Hano Nanami24ORCID,Iwamoto Yuki2,Shirosaki Tomohiro1ORCID,Nagaoka Shoji12ORCID,Oda Reiko456ORCID,Ihara Hirotaka2ORCID,Takafuji Makoto26ORCID

Affiliation:

1. Materials Development Department, Kumamoto Industrial Research Institute, 3-11-38 Higashimachi, Higashi-ku, Kumamoto 862-0901, Japan

2. Department of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

3. International Advanced Energy Science Research and Education Centre, Graduate School of Energy Science, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501, Japan

4. Université de Bordeaux, CNRS, Bordeaux INP, CBMN, UMR 5248, Pessac 33600, France

5. WPI-Advanced Institute for Materials Research, Tohoku University, Katahira, Aoba-Ku, Sendai 980-8577, Japan

6. International Research Organization for Advanced Science & Technology (IROAST), Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

Abstract

Lysine-derived amphiphile assemblies with moderate tightness of packing served as scaffolds for the chiral J-aggregation of cyanine dyes in water. The induced J-aggregates showed high absorption and emission dissymmetry factors in the order of 10−2.

Funder

Japan Society for the Promotion of Science

Centre National de la Recherche Scientifique

Université de Bordeaux

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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