Manipulating charge transfer excited state relaxation and spin crossover in iron coordination complexes with ligand substitution

Author:

Zhang Wenkai12345,Kjær Kasper S.12345,Alonso-Mori Roberto6245,Bergmann Uwe12345,Chollet Matthieu6245,Fredin Lisa A.78910ORCID,Hadt Ryan G.113125,Hartsock Robert W.12345,Harlang Tobias138910,Kroll Thomas624511,Kubiček Katharina141516,Lemke Henrik T.6245,Liang Huiyang W.12345,Liu Yizhu138910,Nielsen Martin M.1718192021,Persson Petter78910ORCID,Robinson Joseph S.6245,Solomon Edward I.624511,Sun Zheng12345,Sokaras Dimosthenis22245,van Driel Tim B.1718192021,Weng Tsu-Chien22245,Zhu Diling6245,Wärnmark Kenneth23118910ORCID,Sundström Villy138910,Gaffney Kelly J.12345

Affiliation:

1. PULSE Institute

2. SLAC National Accelerator Laboratory

3. Stanford University

4. Menlo Park

5. USA

6. LCLS

7. Theoretical Chemistry Division

8. Lund University

9. 22100 Lund

10. Sweden

11. Department of Chemistry

12. Stanford

13. Department of Chemical Physics

14. Max Planck Institute for Biophysical Chemistry

15. Göttingen

16. Germany

17. Centre for Molecular Movies

18. Department of Physics

19. Technical University of Denmark

20. Lyngby

21. Denmark

22. SSRL

23. Centre for Analysis and Synthesis

Abstract

Optical and X-ray free-electron laser measurements reveal ligand substitution in an Fe(ii)-centered complex extends its MLCT lifetime.

Funder

Office of Science

National Science Foundation

European Research Council

Deutsche Forschungsgemeinschaft

Volkswagen Foundation

Danish National Research Foundation

Carlsberg Foundation

Danish Council for Independent Research

Crafoord Foundation

Swedish Research Council

Knut and Alice Wallenberg Foundation

Swedish Energy Agency

Achievement Rewards for College Scientists Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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