Two-dimensional materials as a stabilized interphase for the solid-state electrolyte Li10GeP2S12 in lithium metal batteries

Author:

Ma Jiachen12345ORCID,Quhe Ruge67895ORCID,Zhang Zheyu12345,Yang Chen12345ORCID,Zhang Xiuying12345ORCID,Li Jingzhen12345ORCID,Xu Lin1045ORCID,Yang Jie12345,Shi Bowen12345,Liu Shiqi12345ORCID,Xu Linqiang12345,Sun Xiaotian111213145ORCID,Lu Jing12345

Affiliation:

1. State Key Laboratory for Mesoscopic Physics

2. Department of Physics

3. Peking University

4. Beijing 100871

5. P. R. China

6. State Key Laboratory of Information Photonics and Optical Communications

7. School of Science

8. Beijing University of Posts and Telecommunications

9. Beijing 100876

10. Collaborative Innovation Center of Quantum Matter

11. College of Chemistry and Chemical Engineering

12. Henan Key Laboratory of Function-Oriented Porous Materials

13. Luoyang Normal University

14. Luoyang 471934

Abstract

An efficient screening procedure for two-dimensional (2D) solid-electrolyte interphases (SEIs) is designed. In the concrete case, the two selected 2D SEIs (h-BN and α-BNyne) do stabilize the interface between the solid-state electrolyte Li10GeP2S12 and the lithium metal anode, blocking the electron transfer and maintaining the Li-ion flow.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

State Key Laboratory of Information Photonics and Optical Communications

Peking University

Beijing University of Posts and Telecommunications

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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