The direct observation of the doorway 1nπ* state of methylcinnamate and hydrogen-bonding effects on the photochemistry of cinnamate-based sunscreens-Reference-Cited by-同舟云学术

The direct observation of the doorway 1nπ* state of methylcinnamate and hydrogen-bonding effects on the photochemistry of cinnamate-based sunscreens

Published:2019 Issue:36 Volume:21 Page:19755-19763
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kinoshita Shin-nosuke¹²³⁴⁵,Inokuchi Yoshiya¹²³⁴⁵^ORCID,Onitsuka Yuuki¹²³⁴⁵,Kohguchi Hiroshi¹²³⁴⁵,Akai Nobuyuki⁶⁷⁸⁵,Shiraogawa Takafumi⁹¹⁰¹¹⁵^ORCID,Ehara Masahiro⁹¹⁰¹¹⁵¹²^ORCID,Yamazaki Kaoru¹³¹⁴¹⁵⁵,Harabuchi Yu¹¹⁶¹⁷¹⁸⁵,Maeda Satoshi¹¹⁶¹⁷¹⁸⁵^ORCID,Ebata Takayuki¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Hiroshima University

4. Higashi-Hiroshima 739-8526

5. Japan

6. Graduate School of Bio-Applications and Systems Engineering (BASE)

7. Tokyo University of Agriculture and Technology

8. Tokyo 184-8588

9. SOKENDAI, the Graduate University for Advanced Studies

10. Myodaiji

11. Okazaki 444-8585

12. Institute for Molecular Science and Research Center for Computational Science

13. Institute for Materials Research

14. Tohoku University

15. Sendai

16. Faculty of Science

17. Hokkaido University

18. Sapporo 060-0810

Abstract

The electronic states and photochemistry including nonradiative decay (NRD) and trans(E) → cis(Z) isomerization of methylcinnamate (MC) and its hydrogen-bonded complex with methanol have been investigated under jet-cooled conditions.

Funder

Japan Society for the Promotion of Science

Japan Science and Technology Agency

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP02914A

Reference55 articles.

1. Probing the Photochemical Mechanism in Photoactive Yellow Protein