Phosphinoquinoline supported CoII, NiII, and FeII complexes: divergent behaviour upon reduction

Author:

Schiltz Pauline1,Casaretto Nicolas1ORCID,Bourcier Sophie1ORCID,Auffrant Audrey1ORCID,Gosmini Corinne1ORCID

Affiliation:

1. Laboratoire de Chimie Moléculaire (LCM), CNRS, Ecole Polytechnique, Institut Polytechnique de Paris, Route de Saclay, 91120 Palaiseau, France

Abstract

The reduction of a phosphinoquinoline supported CoII complex led to ligand coupling and the isolation of a CoII complex featuring a (PNNP) ligand, while the reduction of NiII complexes occured under the same conditions at the metal led to a Ni0 trimer.

Funder

Centre National de la Recherche Scientifique

École Polytechnique Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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