Fe(<scp>ii</scp>) complexes of pyridine-substituted thiosemicarbazone ligands as catalysts for oxidations with hydrogen peroxide-Reference-Cited by-同舟云学术

Fe(ii) complexes of pyridine-substituted thiosemicarbazone ligands as catalysts for oxidations with hydrogen peroxide

Published:2023 Issue:40 Volume:52 Page:14606-14612
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Castillo Carmen E.¹^ORCID,Gonzálvez Miguel A.²^ORCID,Algarra Andrés G.¹^ORCID,Fernández-Trujillo M. Jesús¹^ORCID,Ferrer Montserrat²³^ORCID,Martínez Manuel²³^ORCID,Basallote Manuel G.¹^ORCID

Affiliation:

1. Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Instituto de Biomoléculas (INBIO), Universidad de Cádiz, Apartado 40, E-11510 Puerto Real, Cádiz, Spain

2. Departament de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Universitat de Barcelona, Martí i Franquès 1-11, E-08028 Barcelona, Spain

3. Institute of Nanoscience and Nanotechnology (IN2UB), Universitat de Barcelona, 08028 Barcelona, Spain

Abstract

[FeII(TSC)2] complexes selectively catalyze oxidation of styrene to benzaldehyde with H2O2. These iron complexes, the free TSC ligands, and [Zn(Dp44mT)2] also catalyze sulfoxidation of thioanisole, but only the iron complexes catalyze styrene oxidation.

Funder

European Regional Development Fund

Consejería de Economía, Innovación, Ciencia y Empleo, Junta de Andalucía

Ministerio de Ciencia, Innovación y Universidades

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02442C

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