Structures of dimetallocenes M2(C5H5)2 (M = Zn, Cu, Ni, Co, Fe) and their perfluorinated derivatives-Reference-Cited by-同舟云学术

Structures of dimetallocenes M2(C5H5)2 (M = Zn, Cu, Ni, Co, Fe) and their perfluorinated derivatives

Published:2017 Issue:13 Volume:41 Page:5924-5933
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Li Jing¹²³⁴⁵,Li Guoliang¹²³⁴⁵,Xie Yaoming⁶⁷⁸⁹,King R. Bruce¹²³⁴⁵^ORCID,Schaefer Henry F.⁶⁷⁸⁹^ORCID

Affiliation:

1. MOE Key Laboratory of Theoretical Chemistry of the Environment

2. Center for Computational Quantum Chemistry

3. South China Normal University

4. Guangzhou 510006

5. P. R. China

6. Department of Chemistry and Center for Computational Chemistry

7. University of Georgia

8. Athens

9. USA

Abstract

Density functional theory shows that the dizincocenes Zn₂(C₅X₅)₂ (X = H, F) have singlet coaxial structures with two (η⁵-C₅X₅)Zn units linked by a Zn–Zn single bond. However, the low-energy M₂(C₅H₅)₂ (M = Cu–Fe) structures have perpendicular configurations with bridging C₅H₅ ligands.

Funder

Division of Chemistry

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C7NJ01105A

Reference35 articles.

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2. The Dichotomy of Dimetallocenes: Coaxial versus Perpendicular Dimetal Units in Sandwich Compounds

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4. Preparation and structure of two binuclear sandwich benzene-metal complexes of palladium

5. Metal–Metal and Metal–Ligand Bonds in (η5-C5H5)2M2 (M = Be, Mg, Ca, Ni, Cu, Zn)

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