Frustrated N-heterocyclic carbene–silylium ion Lewis pairs-Reference-Cited by-同舟云学术

Frustrated N-heterocyclic carbene–silylium ion Lewis pairs

Published:2015 Issue:20 Volume:44 Page:9400-9408
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Silva Valverde Miguel F.¹²³⁴,Theuergarten Eileen¹²³⁴,Bannenberg Thomas¹²³⁴,Freytag Matthias¹²³⁴,Jones Peter G.¹²³⁴,Tamm Matthias¹²³⁴

Affiliation:

1. Technische Universität Braunschweig

2. Institut für Anorganische und Analytische Chemie

3. 38106 Braunschweig

4. Germany

Abstract

The reaction of a sterically demanding NHC affords frustrated carbene-trimethylsilylium ion pairs, which exhibit FLP-type reactivity such as carbon dioxide fixation and metal–halide bond activation.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01362C

Reference85 articles.

1. Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes

2. Dihydrogen Activation with tBu3P/B(C6F5)3: A Chemically Competent Indirect Mechanism via in Situ-Generated p-tBu2P–C6F4–B(C6F5)2

3. Turning Frustration into Bond Activation: A Theoretical Mechanistic Study on Heterolytic Hydrogen Splitting by Frustrated Lewis Pairs

4. The Mechanism of Dihydrogen Activation by Frustrated Lewis Pairs Revisited

5. Reactivity Models of Hydrogen Activation by Frustrated Lewis Pairs: Synergistic Electron Transfers or Polarization by Electric Field?

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