Modulating proton diffusion and conductivity in metal–organic frameworks by incorporation of accessible free carboxylic acid groups

Author:

Rought Peter1234,Marsh Christopher1234ORCID,Pili Simona1234,Silverwood Ian P.5674ORCID,Sakai Victoria García5674,Li Ming89104ORCID,Brown Martyn S.1234,Argent Stephen P.111124ORCID,Vitorica-Yrezabal Inigo1234,Whitehead George1234ORCID,Warren Mark R.13144,Yang Sihai1234ORCID,Schröder Martin1234ORCID

Affiliation:

1. School of Chemistry

2. University of Manchester

3. Manchester M13 9PL

4. UK

5. ISIS Pulsed Neutron and Muon Source

6. Rutherford Appleton Laboratory

7. Oxfordshire OX11 0QX

8. School of Engineering

9. University of Nottingham

10. Nottingham NG7 2RD

11. University of Warwick

12. Coventry CV4 7AL

13. Diamond Light Source

14. Oxfordshire OX11 0DE

Abstract

The proton conductivity of barium-based MOFs MFM-510 to MFM-512 are analysed in relation to the absence and presence of free –COOH groups in the pores.

Funder

H2020 European Research Council

Engineering and Physical Sciences Research Council

Royal Society

University of Manchester

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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