High-efficiency activation of the C–H bond to synthesize <i>p</i>-methoxy benzaldehyde over a MnO<sub>2</sub>/CNT/Gr catalyst-Reference-Cited by-同舟云学术

High-efficiency activation of the C–H bond to synthesize p-methoxy benzaldehyde over a MnO₂/CNT/Gr catalyst

Published:2022 Issue:20 Volume:46 Page:9755-9761
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Wu Yi¹²³,Tang Mengyi¹²³,Zhong Yan⁴^ORCID,Guo Zhenlong¹²³,Li Kexin¹²³,Yang Youdi¹^ORCID,Li Qiang¹²³^ORCID

Affiliation:

1. College of Science, Beijing Forestry University, Beijing, 100083, China

2. College of Biological Sciences and Biotechnology, Beijing Forestry University, Beijing, 100083, China

3. Beijing Key Laboratory of Forest Food Processing and Safety, Beijing, 100083, China

4. College of Material Science and Technology, Beijing Forestry University, Beijing, 100083, China

Abstract

The selective oxidation of C(sp3)–H was achieved by the MnO2/CNTs/Gr electrocatalyst: 81.03% faradaic efficiency and 82.73% selectivity of p-methoxy benzaldehyde were obtained.

Funder

Central University Basic Research Fund of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ00589A

Reference42 articles.

1. Photochemical C–H Activation Enables Nickel-Catalyzed Olefin Dicarbofunctionalization

2. Special-selective C–H oxidation of toluene to benzaldehyde by a hybrid polyoxometalate photocatalyst including a rare [P6W48Fe6O180]30– anion

3. Electrochemical Cobalt-Catalyzed C–H Oxygenation at Room Temperature

4. One-pot synthesis of bio-based polycarbonates from dimethyl carbonate and isosorbide under metal-free condition

5. Iron-catalyzed oxidative functionalization of C(sp3)–H bonds under bromide-synergized mild conditions

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