Suzuki–Miyaura catalyst-transfer polymerization: new mechanistic insights

Author:

Howell Mitchell T.1,Kei Peter2,Anokhin Maksim V.1,Losovyj Yaroslav34,Fronczek Frank R.2,Nesterov Evgueni E.12ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, Illinois 60115, USA

2. Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, USA

3. Department of Chemistry, Indiana University, Bloomington, Indiana 47401, USA

4. Department of Physics and Astronomy, University of Nebraska, Lincoln, Nebraska 68588, USA

Abstract

Selective enhancement of the oxo-palladium transmetalation pathway in Ag+-mediated Suzuki–Miyaura catalyst transfer polymerization enables direct participation of N-methyliminodiacetic acid (MIDA) boronates in the polymerization process.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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