Fe3O4@l-Proline/Pd nanocomposite for one-pot tandem catalytic synthesis of (±)-warfarin from benzyl alcohol: synergistic action of organocatalyst and transition metal catalyst
Author:
Affiliation:
1. Department of Chemistry
2. Faculty of Science
3. The Maharaja Sayajirao University of Baroda
4. Vadodara-390 002
5. India
Abstract
One-pot synthesis of (±)-warfarin from scratch! The reported catalytic nanocomposite can carry out 3-way catalysis, namely, oxidation, aldol condensation and Michael addition, in a tandem fashion in PEG-400 and water as 'green' reaction media.
Funder
Science and Engineering Research Board
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CY/C9CY01497G
Reference52 articles.
1. Organocatalytic Asymmetric Michael Reaction of Cyclic 1,3-Dicarbonyl Compounds andα,β-Unsaturated Ketones—A Highly Atom-Economic Catalytic One-Step Formation of Optically Active Warfarin Anticoagulant
2. Highly Enantioselective Michael Addition of Cyclic 1,3-Dicarbonyl Compounds to α,β-Unsaturated Ketones
3. Substrate-Directed Stereoselectivity in Vicinal Diamine-Catalyzed Synthesis of Warfarin
4. Organocatalytic Synthesis of Drugs and Bioactive Natural Products
5. Anticoagulant activity of the enantiomers of acenocoumarol.
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