Liquid–liquid extraction of alkali cations by 18-crown-6: complexation and interface crossing studied by MD and PMF simulations
Author:
Affiliation:
1. Laboratoire MSM
2. UMR 7140
3. Institut de Chimie
4. 67000 Strasbourg
5. France
Abstract
The 18C6/M+Pic−complexes form and adsorb “right at the nano-interface” where 18C6 prefers the K+guest.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2016/NJ/C5NJ02609A
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2. L. Cecille , M.Casarci and L.Pietrelli, New Separation Chemistry Techniques for Radioactive Waste and other Specific Applications, Commission of the European Communities, Elsevier Applied Science, London New York, 1991
3. Cyclic polyethers and their complexes with metal salts
4. The Discovery of Crown Ethers (Noble Lecture)
5. The Design of Molecular Hosts, Guests, and Their Complexes (Nobel Lecture)
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