Charge state-dependent catalytic activity of [Au25(SC12H25)18] nanoclusters for the two-electron reduction of dioxygen to hydrogen peroxide-Reference-Cited by-同舟云学术

Charge state-dependent catalytic activity of [Au25(SC12H25)18] nanoclusters for the two-electron reduction of dioxygen to hydrogen peroxide

Published:2014 Issue:62 Volume:50 Page:8464-8467
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Lu Yizhong¹²³⁴⁵,Jiang Yuanyuan¹²³⁴⁵,Gao Xiaohui¹²³⁴⁵,Chen Wei¹²³⁴

Affiliation:

1. State Key Laboratory of Electroanalytical Chemistry

2. Changchun Institute of Applied Chemistry

3. Chinese Academy of Sciences

4. Changchun 130022, China

5. University of Chinese Academy of Sciences

Abstract

The electrocatalytic activity of [Au₂₅(SC₁₂H₂₅)₁₈] clusters for H₂O₂ production from O₂ is dependent on the charge state (−1, 0 and +1), and the maximum H₂O₂ production (∼90%) is from the negative one.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC01841A

Reference23 articles.

1. Oxygen Electroreduction Catalyzed by Gold Nanoclusters: Strong Core Size Effects

2. Sub-nanometre sized metal clusters: from synthetic challenges to the unique property discoveries

3. Quantum sized, thiolate-protected gold nanoclusters

4. Precursor engineering and controlled conversion for the synthesis of monodisperse thiolate-protected metal nanoclusters

5. Au25@SiO2: Quantum Clusters of Gold Embedded in Silica

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