Selective C–C coupling at a Pt(iv) centre: 100% preference for sp2–sp3 over sp3

Selective C–C coupling at a Pt(iv) centre: 100% preference for sp2–sp3 over sp3–sp3

Published:2017 Issue:14 Volume:46 Page:4768-4776
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shaw Paul A.¹²³⁴,Rourke Jonathan P.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Warwick University

3. Coventry

4. UK

Abstract

Oxidative addition of alkyl halides to platinum(ii) gives six-coordinate platinum(iv) complexes that spontaneously reductively couple with complete selectivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00328E

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