Selective C–C coupling at a Pt(iv) centre: 100% preference for sp2–sp3 over sp3–sp3

Author:

Shaw Paul A.1234,Rourke Jonathan P.1234ORCID

Affiliation:

1. Department of Chemistry

2. Warwick University

3. Coventry

4. UK

Abstract

Oxidative addition of alkyl halides to platinum(ii) gives six-coordinate platinum(iv) complexes that spontaneously reductively couple with complete selectivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference48 articles.

1. Activation of C−H Bonds by Metal Complexes

2. A. S. Goldman and K. I.Goldberg, in Activation and Functionalization of C-H Bonds, ed. K. I. Goldberg and A. S. Goldman, ACS, Washington DC, 2004, vol. 885, ACS Symposium Series

3. Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

4. Towards mild metal-catalyzed C–H bond activation

5. Designing Catalysts for Functionalization of Unactivated C–H Bonds Based on the CH Activation Reaction

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