The effect of fluorine substituents on the crystal structure and spin crossover behavior of the cation [MnIII(3,5-diHal-sal2323)]+ complex family with BPh4 anions-Reference-Cited by-同舟云学术

The effect of fluorine substituents on the crystal structure and spin crossover behavior of the cation [Mn^III(3,5-diHal-sal₂323)]⁺ complex family with BPh₄ anions

Published:2022 Issue:35 Volume:46 Page:16880-16888
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Tiunova A. V.¹²,Kazakova A. V.²^ORCID,Korchagin D. V.²^ORCID,Shilov G. V.²,Zakharov K. V.¹,Vasiliev A. N.¹³^ORCID,Yagubskii E. B.²

Affiliation:

1. Lomonosov Moscow State University, 119991 Moscow, Russia

2. Institute of Problems of Chemical Physics RAS, 142432 Chernogolovka, MD, Russia

3. National University of Science and Technology “MISiS”, 119049 Moscow, Russia

Abstract

The effect of fluorine substituents on the structure and magnetic behavior of [Mn(R′,R′′-sal2323)]BPh4 complexes was studied and compared it with that of chlorine and bromine substituents.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ02872G

Reference46 articles.

1. Emerging trends in spin crossover (SCO) based functional materials and devices

2. Molecular spins for quantum computation

3. Manipulating Spin Transition To Achieve Switchable Multifunctions