Alkylthiol surface engineering: an effective strategy toward enhanced electrocatalytic N2-to-NH3 fixation by a CoP nanoarray-Reference-Cited by-同舟云学术

Alkylthiol surface engineering: an effective strategy toward enhanced electrocatalytic N2-to-NH3 fixation by a CoP nanoarray

Published:2021 Issue:24 Volume:9 Page:13861-13866
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Du Zhaobai¹²³⁴,Liang Jie⁵²³⁴,Li Shaoxiong⁵²³⁴,Xu Zhaoquan¹²³⁴,Li Tingshuai¹²³⁴,Liu Qian⁶⁷⁸⁴^ORCID,Luo Yonglan⁶⁷⁸⁴^ORCID,Zhang Fang⁹¹⁰⁴,Liu Yang¹¹¹²¹³⁴,Kong Qingquan⁶⁷⁸⁴,Shi Xifeng¹⁴¹⁵¹⁶¹⁷⁴,Tang Bo¹⁴¹⁵¹⁶¹⁷⁴^ORCID,Asiri Abdullah M.¹⁸¹⁹²⁰²¹²²^ORCID,Li Baihai¹²³⁴^ORCID,Sun Xuping⁵²³⁴^ORCID

Affiliation:

1. School of Materials and Energy

2. University of Electronic Science and Technology of China

3. Chengdu 610054

4. China

5. Institute of Fundamental and Frontier Sciences

6. Institute for Advanced Study

7. Chengdu University

8. Chengdu 610106

9. National Engineering Research Center for Nanotechnology

10. Shanghai 200241

11. School of Materials Science and Engineering

12. Henan Normal University

13. Xinxiang 453007

14. College of Chemistry

15. Chemical Engineering and Materials Science

16. Shandong Normal University

17. Jinan 250014

18. Chemistry Department

19. Faculty of Science & Center of Excellence for Advanced Materials Research

20. King Abdulaziz University

21. Jeddah 21589

22. Saudi Arabia

Abstract

Building a hydrophobic self-assembled monolayer of octadecanethiol on a CoP nanoarray on a titanium mesh (C18@CoP/TM) greatly enhances the N₂ reduction activity with an NH₃ yield of 1.44 × 10⁻¹⁰ mol s⁻¹ cm⁻² and a FE of 14.03% in 0.1 M Na₂SO₄.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/TA/D1TA02424H

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