An unprecedented stereoselective base-induced trimerization of an α-bromovinylsulfone
Author:
Affiliation:
1. School of Chemistry
2. The Bio21 Institute
3. The University of Melbourne
4. Melbourne
5. Australia
6. School of Chemistry & Molecular Biosciences
7. The University of Queensland
8. Brisbane
Abstract
A unprecedented base-induced trimerization of bromovinylsulfone 1 afforded the cyclohexene 6 as a single diastereoisomer.
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB01121K
Reference14 articles.
1. The chemistry of α, β-unsaturated sulfoxides and sulfones: an update
2. The chemistry of vinyl sulphones
3. Remarkably Facile Hexatriene Electrocyclizations as a Route to Functionalized Cyclohexenones via Ring Expansion of Cyclobutenones
4. Reaction of 1-bromovinyl and 1-bromo-2-phenylvinyl sulfones with some CH acids
5. A versatile synthesis of 2,4-substituted oxazoles
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1. Cs2CO3-Mediated Regio- and Stereoselective Sulfonylation of 1,1-Dibromo-1-alkenes with Sodium Sulfinates;Synthesis;2020-10-06
2. A mild light-induced cleavage of the S–O bond of aryl sulfonate esters enables efficient sulfonylation of vinylarenes;Chemical Science;2018
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