Proton reduction by a nickel complex with an internal quinoline moiety for proton relay-Reference-Cited by-同舟云学术

Proton reduction by a nickel complex with an internal quinoline moiety for proton relay

Published:2016 Issue:31 Volume:18 Page:21640-21650
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Majee Karunamay¹²³⁴⁵,Patel Jully¹²³⁴⁵,Rai Surabhi¹²³⁴⁵,Das Babulal⁶⁷⁵,Panda Binata⁸⁹³⁴⁵,Padhi Sumanta Kumar¹²³⁴⁵

Affiliation:

1. Artifcial Photosynthesis Laboratory

2. Department of Applied Chemistry

3. Indian School of Mines

4. Dhanbad

5. India

6. Department of Chemistry

7. Indian Institute of Technology Guwahati

8. Department of Applied Physics

9. String Theory Lab

Abstract

A dicarboxamide based nickel complex with an internal quinoline moiety, acts as an active photocatalyst for proton reduction achieving 2160 turnovers. The pendant base functions for internal proton relay towards the metal center to generate H₂ following a CECE (C = Chemical, E = Electrochemical) mechanistic path.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03034C

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