Nucleofugality hierarchy, in the aminolysis reaction of 4-cyanophenyl 4-nitrophenyl carbonate and thionocarbonate. Experimental and theoretical study-Reference-Cited by-同舟云学术

Nucleofugality hierarchy, in the aminolysis reaction of 4-cyanophenyl 4-nitrophenyl carbonate and thionocarbonate. Experimental and theoretical study

Published:2021 Issue:26 Volume:45 Page:11495-11505
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Montecinos Rodrigo¹²³⁴⁵^ORCID,Aliaga Margarita E.¹²³⁴⁵^ORCID,Pavez Paulina¹²³⁴⁵^ORCID,Cornejo Patricio¹²³⁴⁵,Santos José G.¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Quimica Fisica

2. Facultad de Química y de Farmacia

3. Pontificia Universidad Católica de Chile

4. Santiago

5. Chile

Abstract

Brønsted plot of the reaction of 9 with secondary alicyclic amines. The concave upward non-linear plot is in accordance with two parallel mechanistic pathways.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D0NJ05837H

Reference67 articles.

1. A Practical Guide for Estimating Rates of Heterolysis Reactions

2. Kinetics of the Solvolyses of Benzhydryl Derivatives: Basis for the Construction of a Comprehensive Nucleofugality Scale

3. Solvolytic Reactivity of 2,4-Dinitrophenolates

4. Nucleofugality of Pentafluorophenolate in Various Solvents: Solvolytic Behavior of Phenolates

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