Tuning the nuclearity of [Mo2O2S2]2+-based assemblies by playing with the degree of flexibility of bis-thiosemicarbazone ligands

Author:

Cebotari Diana12,Calancea Sergiu1,Marrot Jerôme1,Guillot Régis3ORCID,Falaise Clément1ORCID,Guérineau Vincent4,Touboul David4,Haouas Mohamed1ORCID,Gulea Aurelian2ORCID,Floquet Sébastien1ORCID

Affiliation:

1. Institut Lavoisier de Versailles, CNRS, UVSQ, Université Paris-Saclay, 45 Av. des Etats-Unis, 78035 Versailles, France

2. State University of Moldova, MD-2009 Chisinau, Republic of Moldova

3. Institut de Chimie Moléculaire et des Matériaux d'Orsay, ICMMO, CNRS UMR 8182, Université Paris Saclay, 91405 Orsay Cedex, France

4. Institut de Chimie des Substances Naturelles, CNRS UPR2301, Université Paris-Sud, Université Paris-Saclay, 91198 Gif-sur-Yvette Cedex, France

Abstract

Two families of binuclear or tetranuclear [MoV2O2S2]2+-based thiosemicarbazone complexes are obtained by varying the rigidity/flexibility of bis-thiosemicarbazone ligands.

Funder

Université de Versailles Saint-Quentin-en-Yvelines

Centre National de la Recherche Scientifique

Agenţia Naţională pentru Cercetare şi Dezvoltare

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference55 articles.

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2. L. B.Maia , I.Moura and J. J. G.Moura , Molybdenum and Tungsten-Containing Enzymes: An Overview , Molybdenum and Tungsten Enzymes , RSC , 2017 , ch. 1, pp. 1–80

3. M. L.Kirk , Spectroscopic and Electronic Structure Studies of Mo Model Compounds and Enzymes , Molybdenum and Tungsten Enzymes , RSC , 2017 , ch. 2, pp. 13–59

4. Di-.mu.-oxo, .mu.-oxo-.mu.-sulfido, and di-.mu.-sulfido complexes of molybdenum(V) with EDTA, cysteine, and cysteine ester ligands. Preparation and electrochemical and spectral properties

5. Structural aspects of molybdenum(IV), molybdenum(V) and molybdenum(VI) complexes

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