Lanthanide contraction and chelating effect on a new family of lanthanide complexes with tetrakis(O-isopropyl)methyle-nediphosphonate: synthesis, structures and terahertz time-domain spectroscopy

Author:

Ma Yan1234,Yang Yong-Sheng1234,Jiang Yu-Han1234,Li Yue-Xue1234,Liu Min5674,Li Zhong-Feng1234,Han Hong-Liang1234,Yang Yu-Ping89104,Xin Xiu-Lan111234,Jin Qiong-Hua1234ORCID

Affiliation:

1. Department of Chemistry

2. Capital Normal University

3. Beijing 100048

4. China

5. The College of Materials Science and Engineering

6. Beijing University of Technology

7. Beijing 100022

8. School of Science

9. Minzu University of China

10. Beijing 100081

11. School of Food and Chemical Engineering

12. Beijing Technology and Business University

Abstract

Sixteen lanthanide–diphosphate complexes have been synthesized by the reaction of lanthanide chlorides and tetrakis(O-isopropyl)methylenediphosphonate ligand in the solvent of acetonitrile (with ethanol or DMF) at room temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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