1,2,3-Triazolylidene ruthenium(ii)(η6-arene) complexes: synthesis, metallation and reactivity-Reference-Cited by-同舟云学术

1,2,3-Triazolylidene ruthenium(ii)(η6-arene) complexes: synthesis, metallation and reactivity

Published:2014 Issue:34 Volume:43 Page:12842-12850
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Bagh Bidraha¹²³,McKinty Adam M.¹²³,Lough Alan J.¹²³,Stephan Douglas W.¹²³

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto, Canada

Abstract

Three bis(1,2,3-triazolylidene) silver(i) complexes were reacted with [RuCl₂(p-cymene)]₂ and the ruthenium complexes [RCH₂N₂(NMe)C₂Ph]RuCl₂(p-cymene) (R = C₆H₂Me₃4a1, C₆H₂iPr₃4b1, Ph 4c1) were isolated as major products with the minor C(sp²)–H activated products [RCH₂N₂(NMe)C₂C₆H₄]RuCl(p-cymene) (R = C₆H₂Me₃4a2, C₆H₂iPr₃4b2, Ph 4c2) and [(C₆H₄)CH₂N₂(NMe)C₂Ph]RuCl(p-cymene) (4c3).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01174K

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