Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study-Reference-Cited by-同舟云学术

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Experimental evidence of charge transfer in a functionalized hexavanadate: a high resolution X-ray diffraction study

Published:2017 Issue:28 Volume:19 Page:18162-18166
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Xu Xiao¹²³⁴⁵,Spasojević-de Biré Anne¹²³⁴⁵^ORCID,Ghermani Nour Eddine¹²³⁴⁵,Wei Yongge⁶⁷⁸⁹,Novaković Sladjana¹²³⁴¹⁰,Bošnjaković-Pavlović Nada¹²³⁴¹¹,Wu Pingfan¹²¹³¹⁴¹⁵⁹

Affiliation:

1. Université Paris-Saclay

2. CentraleSupelec

3. 92295 Châtenay-Malabry

4. France

5. Laboratory “Structures Propriétés et Modélisation des Solides” (SPMS)

6. Department of Chemistry

7. Tsinghua University

8. 100084 Beijing

9. China

10. Laboratory for Theoretical and Condensed Matter Physics

11. Faculty of Physical Chemistry

12. Institute of POM-based Materials

13. Hubei University of Technology

14. The Synergistic Innovation Center of Catalysis Materials of Hubei Province

15. 430086 Wuhan

Abstract

A high resolution X-ray diffraction study has been carried out on [(C₄H₉)₄N]₂ [V₆O₁₃{(OCH₂)₃CCH₂OCCH₂CH₃}₂] (V6–C3) at 100 K. The V6 core possesses a negative charge, leading to a strong polarization of the anion.

Funder

China Scholarship Council

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja

National Natural Science Foundation of China

Natural Science Foundation of Hubei Province

Wuhan University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP01840A

Reference52 articles.

1. Charge-Transfer Excitons at Organic Semiconductor Surfaces and Interfaces

2. Charge transfer in organic molecules for solar cells: theoretical perspective

3. Control of Charge Transfer in Donor/Acceptor Metal–Organic Frameworks

4. Structural Changes Accompanying Intramolecular Electron Transfer: Focus on Twisted Intramolecular Charge-Transfer States and Structures

5. Theoretical Insights into Photoinduced Charge Transfer and Catalysis at Oxide Interfaces

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4. Destroy the inherent symmetry of vanadium-based inorganic cluster through chiral organic ligand: Synthesis and characterization of a polyoxovanadate-derived amino acid ester hybrid;Journal of Molecular Structure;2019-11

5. Experimental and theoretical insights of functionalized hexavanadates on Na+/K+-ATPase activity; molecular interaction field, ab initio calculations and in vitro assays;Journal of Inorganic Biochemistry;2019-09

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