The missing MIL-101(Mn): geometrically guided synthesis and topologically correlated valence states-Reference-Cited by-同舟云学术

The missing MIL-101(Mn): geometrically guided synthesis and topologically correlated valence states

Published:2022 Issue:23 Volume:9 Page:6124-6132
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Xiao Yonghong¹^ORCID,Li Mian¹²^ORCID,Chen Jian-Rui¹^ORCID,Lian Xin¹³^ORCID,Huang Yong-Liang⁴^ORCID,Huang Xiao-Chun¹²^ORCID

Affiliation:

1. Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, China

2. Chemistry and Chemical Engineering Guangdong Laboratory, Shantou 515031, China

3. School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China

4. Department of Medicinal Chemistry, Shantou University Medical College, Shantou, Guangdong 515041, China

Abstract

Through a geometrically guided approach, i.e. with the aid of pyridyl modulators, the long-sought MIL-101(Mn) structure is finally achieved, which features emergent topologically correlated mixed-valence states that are apt for enzymatic catalysis.

Funder

National Natural Science Foundation of China

Li Ka Shing Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI01894B

Reference50 articles.

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