Multi-nuclear, high-pressure, operando FlowNMR spectroscopic study of Rh/PPh3 – catalysed hydroformylation of 1-hexene-Reference-Cited by-同舟云学术

Multi-nuclear, high-pressure, operando FlowNMR spectroscopic study of Rh/PPh3 – catalysed hydroformylation of 1-hexene

Published:2021 Issue: Volume:229 Page:422-442
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Bara-Estaún Alejandro¹²³⁴⁵^ORCID,Lyall Catherine L.¹²³⁴⁵^ORCID,Lowe John P.¹²³⁴⁵,Pringle Paul G.⁶⁷⁸⁴^ORCID,Kamer Paul C. J.⁹¹⁰¹¹^ORCID,Franke Robert¹²¹³¹¹,Hintermair Ulrich¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University of Bath

3. BA2 7AY Bath

4. UK

5. Dynamic Reaction Monitoring Facility

6. School of Chemistry

7. University of Bristol

8. Bristol BS8 1TS

9. Leibniz Institute for Catalysis

10. 18059 Rostock

11. Germany

12. Evonik Performance Materials GmbH

13. 45772 Marl

Abstract

The hydroformylation of 1-hexene with 12 bar of 1 : 1 H₂/CO in the presence of the catalytic system [Rh(acac)(CO)₂]/PPh₃ was successfully studied by real-time multinuclear high-resolution FlowNMR spectroscopy at 50 °C.

Funder

Royal Society

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/FD/C9FD00145J

Reference54 articles.

1. Hydroformylation of Unsaturated Compounds with a Cobalt Carbonyl Catalyst

2. Applied Hydroformylation