Cu-catalyzed cascade difluoroalkylation/5-<i>endo</i>cyclization/β-fluorine cleavage of ynones-Reference-Cited by-同舟云学术

Cu-catalyzed cascade difluoroalkylation/5-endocyclization/β-fluorine cleavage of ynones

Published:2023 Issue:13 Volume:59 Page:1821-1824
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Su Jingwen¹,Guo Wenbin¹,Liu Yi¹,Kong Lichun¹,Zheng Hanliang¹^ORCID,Zhu Gangguo¹^ORCID

Affiliation:

1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Department of Chemistry, Zhejiang Normal University, 688 Yingbin Road, Jinhua 321004, P. R. China

Abstract

A Cu-catalyzed cascade difluoroalkylation/5-endocyclization/β-fluorine cleavage of ynones is reported, delivering α-monofluoroalkenyl cyclopentanones with high efficiency and stereoselectivity.

Funder

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC06068J

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