Deuterium isotope effects on 17O nuclear shielding in a single water molecule from NMR gas phase measurements

Author:

Makulski Włodzimierz1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Warsaw

3. 02-093 Warsaw

4. Poland

Abstract

The 17O NMR shielding constants of the isolated molecules: H2O, HOD and D2O were measured in the gas phase; the isotope effects were established and small nonadditivity was stated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference15 articles.

1. W. Makulski , 17O and 33S NMR Spectroscopy of Small Molecules in the Gas Phase , in Gas Phase NMR , ed. K. Jackowski and M. Jaszuński , RSC , 2016 , ch. 5, pp. 152–183

2. 17O Nuclear Magnetic Resonance Studies in Water of Different Isotopic Composition

3. Deuterium isotope effects on nuclear shielding constants and spin–spin coupling constants in the ammonium ion, ammonia, and water

4. 17O and 1H NMR spectral parameters in isolated water molecules

5. C. J. Jameson , Fundamental Intramolecular and Intermolecular Information from NMR in the Gas Phase , in Gas Phase NMR , ed. K. Jackowski and M. Jaszunński , RSC, 2016 , ch. 1 pp. 1–51

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