Host–guest molecular interaction promoted urea electrosynthesis over a precisely designed conductive metal–organic framework

Author:

Yuan Menglei12,Chen Junwu12,Zhang Honghua12,Li Qiongguang12,Zhou Le12,Yang Chao123ORCID,Liu Rongji124ORCID,Liu Zhanjun25,Zhang Suojiang12ORCID,Zhang Guangjin123ORCID

Affiliation:

1. CAS Key Laboratory of Green Process Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, 100190, Beijing, China

2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, 100049, Beijing, China

3. Chemistry and Chemical Engineering Guangdong Laboratory, Shantou, 515031, China

4. Inorganic Chemistry I, Ulm University, Ulm, 89081, Germany

5. State Key Laboratory of Coal Conversion, CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001, China

Abstract

A precisely fabricated conductive MOF incorporating unique host–guest interactions can be used to achieve active-site integration and effective electrocatalytic C–N bond coupling for the synthesis of urea.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

International Science and Technology Cooperation Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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