Homoleptic gold(i) N-heterocyclic allenylidene complexes: excited-state properties and lyotropic chromonics

Author:

Xiao Xin-Shan12345,Zou Chao6785,Guan Xiangguo12345,Yang Chen12345,Lu Wei6785,Che Chi-Ming12345

Affiliation:

1. State Key Laboratory of Synthetic Chemistry

2. HKU-CAS Joint Laboratory on New Materials, and Department of Chemistry

3. The University of Hong Kong

4. Hong Kong SAR

5. P. R. China

6. Department of Chemistry

7. South University of Science and Technology of China

8. Shenzhen 518055

Abstract

Phosphorescent Au(i) bis(N-heterocyclic allenylidene) complexes exhibit panchromatic transient absorption upon electronic photo-excitation and can self-organize into lyotropic chromonic mesophases in aqueous solutions.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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