Anion–cation interactions in a series of salts with substituted Hphen, Hbpy and H2bpy cations and [W(CN)8]4− anion: polymer with “super-short” N–H⋯N hydrogen bridges containing exclusively anions and H+-Reference-Cited by-同舟云学术

Anion–cation interactions in a series of salts with substituted Hphen, Hbpy and H2bpy cations and [W(CN)8]4− anion: polymer with “super-short” N–H⋯N hydrogen bridges containing exclusively anions and H+

Published:2021 Issue:48 Volume:50 Page:17981-17987
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jurowska Anna¹^ORCID,Hodorowicz Maciej¹^ORCID,Kruczała Krzysztof¹^ORCID,Szklarzewicz Janusz¹^ORCID

Affiliation:

1. Jagiellonian University, Faculty of Chemistry, Gronostajowa 2, 30-387 Kraków, Poland

Abstract

Ten [W(CN)8]4− complexes with polypyridyl ligands were studied. Unique isocyanide CNH form was observed. The presence of paramagnetic centers, exclusively in a solid state, is connected with a very low energy bands, observed in the NIR spectra.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT03224K

Reference31 articles.

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2. Ion-Pair Charge-Transfer Complexes Based on (o-Phenylenebis(oxamato))cuprate(II) and Cyclic Diquaternary Cations of 1,10-Phenanthroline and 2,2‘-Bipyridine: Synthesis, Crystal Structure, and Physical Properties

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