Cooperative dinitrogen capture by a diboraanthracene/samarocene pair-Reference-Cited by-同舟云学术

Cooperative dinitrogen capture by a diboraanthracene/samarocene pair

Published:2021 Issue:42 Volume:50 Page:15000-15002
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Xu Song¹^ORCID,Essex Laura A.²^ORCID,Nguyen Joseph Q.¹^ORCID,Farias Phillip²^ORCID,Ziller Joseph W.¹^ORCID,Harman W. Hill²^ORCID,Evans William J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of California, Irvine, California 92697-2025, USA

2. Department of Chemistry, University of California, Riverside, California 92521, USA

Abstract

The combination of a boron Lewis acid and a decamethylsamarocene, specifically 9,10-Me2-9,10-diboraanthracene with (C5Me5)2SmII(THF)2, in toluene leads to cooperative reductive capture of N2.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT03220H

Reference39 articles.

1. Recent Advances and Challenges of Electrocatalytic N2 Reduction to Ammonia

2. Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments

3. Development of catalytic nitrogen fixation using transition metal–dinitrogen complexes under mild reaction conditions