Three microporous metal–organic frameworks assembled from dodecanuclear {NiII6LnIII6} subunits: synthesis, structure, gas adsorption and magnetism
Author:
Affiliation:
1. Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry
2. Ministry of Education
3. Tianjin Key Laboratory of Structure and Performance for Functional Molecules
4. College of Chemistry
5. Tianjin Normal University
Abstract
Three microporous MOFs with two different orientated {NiIILnIII}6 subunits exhibit high LnIII-independent gas uptake and absorption selectivity for CO2 as well as LnIII-dominated slow magnetic relaxation and a magnetic cryogenic magnetocaloric effect.
Funder
National Natural Science Foundation of China
Tianjin University
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02816H
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