Synthesis, structure, and electrochemical properties of [LNi(R<sub>f</sub>)(C<sub>4</sub>F<sub>8</sub>)]<sup>−</sup> and [LNi(R<sub>f</sub>)<sub>3</sub>]<sup>−</sup> complexes-Reference-Cited by-同舟云学术

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Synthesis, structure, and electrochemical properties of [LNi(R_f)(C₄F₈)]⁻ and [LNi(R_f)₃]⁻ complexes

Published:2022 Issue:14 Volume:51 Page:5515-5523
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shreiber Scott T.¹^ORCID,Amin Fatema¹^ORCID,Schäfer Sascha A.²^ORCID,Cramer Roger E.³^ORCID,Klein Axel²^ORCID,Vicic David A.¹^ORCID

Affiliation:

1. Department of Chemistry, Lehigh University, 6 E Packer Ave., Bethlehem, PA 18015, USA

2. University of Cologne, Faculty of Mathematics and Natural Sciences, Department of Chemistry, Institute for Inorganic Chemistry, Greinstrasse 6, 50939 Koeln, Germany

3. Department of Chemistry, University of Hawaii, 2545 McCarthy Mall, Honolulu, HI, 96822, USA

Abstract

The new anionic nickelate complexes [(MeCN)Ni(C4F8)(CF3)]−, [(MeCN)Ni(C4F8)(C2F5)]−, [(IMes)Ni(C4F8)(CF3)]−, [(IMes)Ni(CF3)3]− and [(F-NHC)Ni(Rf)3]− (F-NHC = fluorinated NHC) were synthesized and fully characterized.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00511E

Reference36 articles.

1. Electrocatalytic fluoroalkylation of olefins

2. Nickel(IV)-Catalyzed C–H Trifluoromethylation of (Hetero)arenes

3. Nickel-Catalyzed C-H Trifluoromethylation of Electron-Rich Heteroarenes

4. Selective nickel-catalyzed fluoroalkylations of olefins

5. Nickel-Catalyzed Difluoroalkylation–Alkylation of Enamides

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