A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL-Reference-Cited by-同舟云学术

A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

Published:2019 Issue:2 Volume:21 Page:355-360
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Mahmoudi Hamed¹²³⁴⁵,Valentini Federica¹²³⁴⁵,Ferlin Francesco¹²³⁴⁵,Bivona Lucia Anna⁶⁷⁸⁹,Anastasiou Ioannis¹²³⁴⁵,Fusaro Luca⁶⁷⁸⁹,Aprile Carmela⁶⁷⁸⁹,Marrocchi Assunta¹²³⁴⁵,Vaccaro Luigi¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory of Green S.O.C. – Dipartimento di Chimica

2. biologia e Biotecnologie

3. Università degli Studi di Perugia

4. 06123 – Perugia

5. Italy

6. Laboratory of Applied Material Chemistry (CMA)

7. University of Namur

8. 5000 Namur

9. Belgium

Abstract

A new polystyrene-type resin loaded with pincer-type imidazolium ionic tag has been very effective in the immobilization of [PdCl₄]²⁻ palladium complex leading to a very low leaching of the metal during its use in flow.

Funder

Università degli Studi di Perugia

Ministero dell’Istruzione, dell’Università e della Ricerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/GC/C8GC03228A

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2. A general, selective, and facile method for ketone synthesis from acid chlorides and organotin compounds catalyzed by palladium