The influence of hindered rotation on electron transfer and exchange interaction in triarylamine-triptycene-perylene diimide triads-Reference-Cited by-同舟云学术

The influence of hindered rotation on electron transfer and exchange interaction in triarylamine-triptycene-perylene diimide triads

Published:2024 Issue: Volume: Page:
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Roger Chantal¹,Schmiedel Alexander¹,Holzapfel Marco¹,Lukzen Nikita N.²,Steiner Ulrich E.³^ORCID,Lambert Christoph¹⁴^ORCID

Affiliation:

1. Institut für Organische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

2. International Tomography Center, Russia and Novosibirsk State University, Institutskaya 3a, Novosibirsk, Novosibirsk 630090, Russia

3. Department of Chemistry, University of Konstanz, Universitätsstraße 10, 78464 Konstanz, Germany

4. Center for Nanosystems Chemistry, Universität Würzburg, Theodor-Boveri-Weg, D-97074 Würzburg, Germany

Abstract

Intramolecular rotations modulate exchange interaction (J) as well as electronic couplings through variable π-overlap, affecting the rate constants of photoinduced charge separation and recombination in electron-donor-bridge-acceptor triads.

Funder

Ministry of Science and Higher Education of the Russian Federation

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D3CP05785B

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