Design criteria for the competing chlorine and oxygen evolution reactions: avoid the OCl adsorbate to enhance chlorine selectivity-Reference-Cited by-同舟云学术

Design criteria for the competing chlorine and oxygen evolution reactions: avoid the OCl adsorbate to enhance chlorine selectivity

Published:2020 Issue:39 Volume:22 Page:22451-22458
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Exner Kai S.¹²³⁴⁵^ORCID

Affiliation:

1. Sofia University

2. Faculty of Chemistry and Pharmacy

3. Department of Physical Chemistry

4. Sofia 1164

5. Bulgaria

Abstract

The intermediate matters: the concept of ESSI-ΔG₂ activity maps illustrates that the formation of the Cl adsorbate rather than the OCl intermediate is desirable to enhance chlorine selectivity in the competing chlorine and oxygen evolution reactions.

Funder

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP03667F

Reference84 articles.

1. Selectivity between Oxygen and Chlorine Evolution in the Chlor-Alkali and Chlorate Processes

2. The Chlorine Industry

3. Best Available Techniques (B. A. T.) Reference Document for the Production of Chlor-alkali; European Commission JRC, Institute for Prospective Technological Studies European, IPPC Bureau 2014

4. Euro Chlor , Chlorine Industry Review , 2016–2017

5. P. Schmittinger , T.Florkiewicz , L. C.Curlin , B.Lüke , R.Scannell , T.Navin , E.Zelfel and R.Bartsch , Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH , Weinheim, Germany , 2012

Cited by 48 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Stable and efficient chlorine evolution reaction with atomically dispersed Ru on surface tensile strained TiO2;Applied Catalysis B: Environment and Energy;2024-12

2. Selectivity Study of Direct Seawater Electrolyzer Anode Catalysts Using the Rotating Ring-Disc Electrode Method;Journal of The Electrochemical Society;2024-09-02

3. Unraveling the competition between the oxygen and chlorine evolution reactions in seawater electrolysis: Enhancing selectivity for green hydrogen production;Electrochimica Acta;2024-09

4. Manipulating d-Electronic States via Transition Metal Doping in MnO₂ to Boost Direct Seawater Electrolysis;ACS Sustainable Chemistry & Engineering;2024-08-30

5. Theoretical study on the carbon nanomaterial‐supported Pt complex electrocatalysts for efficient and selective chlorine evolution reaction;Journal of Computational Chemistry;2024-07-17